Yes you want to wear rubber gloves especially if your skin is sensitive to such things.
One word worth mentioning some people think using things full strength means better performance. Just the opposite with this stuff. Dilute it according to directions or you are just pouring money out. it work better with hot water as well.
I've spilled it full strength on my bare hands and just wiped it off or rinsed it off with no ill effects but I also grew up washing parts in ethel gasoline with my bare hands.
We used to make our own lye (potassium hydroxide) out of ashes to make soap for washing with when I was a kid

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